Alvarez Pari (Beginning August-2025)
Research
Research
The Personick Group is advancing the state of the art in the synthesis of precise nanomaterials and is using these precision materials to define catalytic structure-function relationships at an elevated level of mechanistic detail. Through this combination of materials synthesis innovations and fundamental studies of catalytic reactivity, we aim to develop principles for the predictive design of catalyst materials that will enable key advances in technology for sustainable energy generation and chemical synthesis.
For decades, the dearomatization of arenes has been recognized as a chemical transformation of fundamental importance. It provides the connection between this robust and abundant source of hydrocarbons and the alicyclic frameworks common to many biologically active products. Thus, dearomatization methods have become powerful tools for organic synthesis.
The Machan Group is interested in energy-relevant catalysis, particularly at the interface of molecular electrochemistry and materials. The development of efficient and selective transformations to produce commodity chemical precursors and fuels using CO2, O2, H2, and H2O as reagents remains an ongoing challenge for the storage of electrical energy within chemical bonds. Our approach is inspired by the numerous metalloproteins capable of catalyzing kinetically challenging reactions with significant energy barriers in an efficient manner under ambient conditions.
Organometallic chemistry, inorganic chemistry, homogeneous catalysis, small molecule activation